Does Toast Titanium have the ability to let me choose the break point between layers on dual-layer media (Verbatim DVD+R DL) -- or is it at least nice enough to set the break point between chapters?

Any recommendations on getting the best quality on a dual-layer project? I have a 100-minute main video and four smaller clips at about five minutes each. My main concern is that the break point can't be in the middle of a chapter as it would cause a break in playback on some DVD players. If there's a short break between scenes, no problem.

I have Toast Titanium 7.1.2 (Intel).

Toast will set the lay break in the best place it can for the project. DVD+R DL require the layer break be place so that both layer 0 and 1 are the same size. It may not be on a chapter though.

The layer break can't be set manually.