Tried these steps Jim as I've noticed it's the same thing I've seen posted in other threads with different issues. The Graphics card is AMD, not Nvidia unfortunately, but I can confirm all drivers are up to date and is running the latest AMD catalyst software. It's Windows 7 by the way.
Capturing is not an issue at least. Captured this morning with no issues using with max settings, for a couple of hours, never any delay, glitches, freezing or anything. Just the Live Streaming aspect is the issue here.